Then to start and stop PulseAudio so that other applications are able to use it:
pulseaudio --startWith PulseAudio stopped you should find that there are a range of options for sound devices. Choose the best option for your hardware and distribution (probably Default) and Skype sound should function.
pulseaudio --kill
A GUI application written in Python to easily turn on and off PulseAudio can be found at PulseAudioControl. To run this application ensure that it is placed in a location that can
be found in the PATH variable and ensure that it has executable
permissions.
The application is very simple and was written using the graphical
rapid application development package Illumination which has been
developed by Radical Breeze. Details about this package can be
found at www.radicalbreeze.com. I
run Ubuntu and have placed PulseAudioControl in the top panel to make
it quick and easy to access. Please feel free to download
PulseAudioControl from the links on this page. You can also
download and use the icon on this page by right clicking and choosing
"Save Image". PulseAudioControl is offered freely without warranty for use at your own discretion under the GPL2 licence.
(The application is currently at alpha version 0.0,
however, it is very simple and appears to be stable and
without issues.)